18,015 research outputs found
Two physical characteristics of numerical apparent horizons
This article translates some recent results on quasilocal horizons into the
language of general relativity so as to make them more useful to
numerical relativists. In particular quantities are described which
characterize how quickly an apparent horizon is evolving and how close it is to
either equilibrium or extremality.Comment: 6 pages, 2 figures, conference proceedings loosely based on talk
given at Theory Canada III (Edmonton, Alberta, 2007). V2: Minor changes in
response to referees comments to improve clarity and fix typos. One reference
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Synthesis of hetero-bifunctional, end-capped oligo-EDOT derivatives
Conjugated oligomers of 3,4-ethylenedioxythiophene (EDOT) are attractive materials for tissue engineering applications, and as model systems for studying the properties of the widely used polymer PEDOT. We report here the facile synthesis of a series of keto-acid end-capped oligo-EDOT derivatives (n = 2-7) through a combination of a glyoxylation end capping strategy and iterative direct arylation chain extension. Importantly, these structures not only represent the longest oligo-EDOTs reported, but are also bench stable in contrast to previous reports on such oligomers. The constructs reported here can undergo subsequent derivatization for integration into higher order architectures, such as those required for tissue engineering applications. The synthesis of hetero-bifunctional constructs, as well as those containing mixed monomer units is also reported, allowing further complexity to be installed in a controlled manner. Finally, we describe the optical and electrochemical properties of these oligomers and demonstrate the importance of the keto-acid in determining their characteristics
Simulations of disk galaxies with cosmic ray driven galactic winds
We present results from high-resolution hydrodynamic simulations of isolated
SMC- and Milky Way-sized galaxies that include a model for feedback from
galactic cosmic rays (CRs). We find that CRs are naturally able to drive winds
with mass loading factors of up to ~10 in dwarf systems. The scaling of the
mass loading factor with circular velocity between the two simulated systems is
consistent with \propto v_c^{1-2} required to reproduce the faint end of the
galaxy luminosity function. In addition, simulations with CR feedback reproduce
both the normalization and the slope of the observed trend of wind velocity
with galaxy circular velocity. We find that winds in simulations with CR
feedback exhibit qualitatively different properties compared to SN driven
winds, where most of the acceleration happens violently in situ near star
forming sites. In contrast, the CR-driven winds are accelerated gently by the
large-scale pressure gradient established by CRs diffusing from the
star-forming galaxy disk out into the halo. The CR-driven winds also exhibit
much cooler temperatures and, in the SMC-sized system, warm (T~10^4 K) gas
dominates the outflow. The prevalence of warm gas in such outflows may provide
a clue as to the origin of ubiquitous warm gas in the gaseous halos of galaxies
detected via absorption lines in quasar spectra.Comment: ApJL accepted. Replaced with accepted version. Minor revision in
response to referee comment
Phase Diagrams For The Blue Phases Of Highly Chiral Liquid Crystals
Polarizing microscopy and optical-activity measurements are used to determine the phase diagram for the blue phases of chiral-racemic mixtures of terephthaloyloxy-bis-4-(2\u27-methylbutyl) benzoate. Contrary to an earlier report, it is the second blue phase (BP II) rather than the first blue phase (BP 1) that is not stable relative to the other blue phases at high chirality. With this development, all phase diagrams for the blue phases reported to date have the same topology. Using similar data for two other highly chiral systems, it is found that a simple scaling of the temperature and chiral-fraction axes produces phase diagrams in quantitative agreement with the present results. Thus, in spite of differences in molecular structure, the number of chiral centers, and phase-transition temperatures, these three systems possess remarkably similar phase diagrams and lend evidence for a universal phase diagram for the blue phases
SPS phase control system performance via analytical simulation
A solar power satellite transmission system which incorporates automatic beam forming, steering, and phase control is discussed. The phase control concept centers around the notation of an active retrodirective phased array as a means of pointing the beam to the appropriate spot on Earth. The transmitting antenna (spacetenna) directs the high power beam so that it focuses on the ground-based receiving antenna (rectenna). A combination of analysis and computerized simulation was conducted to determine the far field performance of the reference distribution system, and the beam forming and microwave power generating systems
Explaining anomalous responses to treatment in the Intensive Care Unit
The Intensive Care Unit (ICU) provides treatment to critically ill patients. When a patient does not respond as expected to such treatment it can be challenging for clinicians, especially junior clinicians, as they may not have the relevant experience to understand the patientâs anomalous response. Datasets for 10 patients from Glasgow Royal Infirmaryâs ICU have been made available to us. We asked several ICU clinicians to review these datasets and to suggest sequences which include anomalous or unusual reactions to treatment. Further, we then asked two ICU clinicians if they agreed with their colleaguesâ assessments, and if they did to provide possible explanations for these anomalous sequences. Subsequently we have developed a system which is able to replicate the cliniciansâ explanations based on the knowledge contained in its several ontologies; further the system can suggest additional explanations which will be evaluated by the senior consultant
Self-contained Kondo effect in single molecules
Kondo coupling of f and conduction electrons is a common feature of
f-electron intermetallics. Similar effects should occur in carbon ring
systems(metallocenes). Evidence for Kondo coupling in Ce(C8H8)2 (cerocene) and
the ytterbocene Cp*2Yb(bipy) is reported from magnetic susceptibility and
L_III-edge x-ray absorption spectroscopy. These well-defined systems provide a
new way to study the Kondo effect on the nanoscale, should generate insight
into the Anderson Lattice problem, and indicate the importance of this
often-ignored contribution to bonding in organometallics.Comment: 4 pages, 5 figures (eps
Worker heterogeneity, new monopsony, and training
A worker's output depends not only on his/her own ability but also on that of colleagues, who can facilitate the performance of tasks that each individual cannot accomplish on his/her own. We show that this common-sense observation generates monopsony power and is sufficient to explain why employers might expend resources on training employees even when the training is of use to other firms. We show that training will take place in better-than-average or âgoodâ firms enjoying greater monopsony power, whereas âbadâ firms will have low-ability workers unlikely to receive much training
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